Accessing Metal-Specific Orbital Interactions in C–H Activation with Resonant Inelastic X-ray Scattering

Chemical Science(2024)

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摘要
We propose, using simulated RIXS signatures, a way of spectroscopically accessing the “two-way” charge transfer interactions between the C–H bond and the metal during C–H activation, thereby verifying and motivating orbital correlation diagrams.
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关键词
C–H Activation,Transition Metal Catalysis,Directed C–H Functionalization,Resonant Inelastic Scattering,Metal-Catalyzed Reactions
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