Emergent Quasi-Two-dimensional Ferromagnetic State with Perpendicular Magnetic Anisotropy at La0.7Sr0.3MnO3/SrCuO2 Interface

Due to the strong interlayer coupling between multiple degrees of freedom, oxide heterostructures usually produce distinct interfacial phases with unexpected functionalities. Here, we report on the realization of quasi-two-dimensional ferromagnetic state in ultrathin La0.7Sr0.3MnO3 (LSMO) layer down to two unit cells (u.c.), being sandwiched by the planar infinite-layer structured SrCuO2 layers (P-SCO). We find the LSMO/P-SCO interface coupling has greatly suppressed the magnetic dead layer of LSMO, resulting in an emergent interfacial ferromagnetic phase. Thus, robust ferromagnetic order can be maintained in the 2 u.c.-thick LSMO layer (∼7.7 Å), showing a Curie temperature of ∼260 K and remarkable perpendicular magnetic anisotropy. X-ray absorption spectra reveal notable charge transfer from Mn to Cu at the interface, and thus, resulted preferential d3z2−r2 orbital occupation for interfacial Mn ions plays an important role in the inducing of perpendicular magnetic anisotropy in quasi-two-dimensional LSMO layer. Our work demonstrates a unique approach for tuning the properties of oxides via an interface engineering of oxygen coordination in perovskite/infinite-layer heterostructures.