Highly Selective Aerobic Oxidation of Cyclohexane by Flower-Like MoO3-x 3-X Microspheres-Nitrogen-doped Carbon Dots Heterojunction

Due to the higher susceptibility of alcohols and ketones to oxidation compared to alkanes, converting inert C-H bonds in alkanes into high value-added product KA oil with high selectivity is still a significant obstacle. In this study, flower-like microspheres of MoO3-x, 3-x , featuring aligned nanosheets and oxygen vacancies, were combined with nitrogen doped carbon dots (NCDs) to fabricate S-scheme heterojunctions of MoO3-x-NCDs 3-x-NCDs for boosting the photocatalytic efficiency in oxidizing cyclohexane. Because of the oxygen vacancies-triggered localized surface plasmon resonance (LSPR) and the S-scheme charge transfer mechanism, there was a significant improvement in the absorption of visible light and an enhancement in the efficiency of charge separation. The MoO3-x-NCDs 3-x-NCDs composites exhibited a notably improved catalytic performance in cyclohexane oxidation. The MoO3-x-NCDs 3-x-NCDs composite exhibited remarkable selectivity of KA oil in catalyzing cyclohexane oxidation under light exposure, attributed to the substantial increase in cyclohexane adsorption capacity. The highest cyclohexane transformation rate of 9.98 % was achieved by MoO3-x-NCDs-2 3-x-NCDs-2 composites with a MoO3-x/NCDs 3-x /NCDs ratio of 50:1, outperforming bare MoO3-x 3-x by 1.81 times, while exhibiting a KA oil selectivity reaching 93.75 %. The mechanism of selective photocatalytic oxidation was explored using photoelectric examination, analysis of energy bands, and evaluation of active radicals. In this research, green photocatalysts were fabricated through the utilization of NCDs, enabling efficient conversion and selective oxidation of cyclohexane in gentle environments. This innovative approach holds great potential for advancing the field of photocatalysis.