An Insight into Synergistic Effect of Polyaniline and Noble Metal (ag) on Vanadium Pentoxide Nanorods for Enhanced Energe Storage Performance

JOURNAL OF THE INDIAN CHEMICAL SOCIETY(2024)

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摘要
The widespread applications of vanadium pentoxide (V2O5) are limited because of its low electrical conductivity and restricted ion diffusion coefficient. To address these constraints, the present study includes a straightforward and effective approach for fabricating polyaniline based silver-decorated vanadium pentoxide (Ag-V2O5/PANi) as an electrode material. The structural and morphological investigation of prepared electrode materials were made by X-ray diffraction analysis and scanning electron microscopy respectively. In comparison to pure Ag-V2O5, the Ag-V2O5/PANi composite demonstrated enhanced performance in various aspects. Specifically, the Ag-V2O5/PANi showed a higher specific capacitance (628 Fg-1) when subjected to a current density (1 Ag- 1 ) in KOH electrolyte. Additionally, it has an energy density of 153 Whkg-1. Furthermore, the Ag-V2O5/PANi composite exhibited superior stability even after undergoing 3000 charge to discharge cycles. Exceptional capabilities shown can be ascribed to synergistic interaction between PANi and Ag-V2O5. The remarkable outcomes obtained from these electrode materials have the potential to foster novel prospects in high-energy-density storage systems.
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关键词
Silver,Polyaniline,Supercapacitor,EIS,V 2 O 5
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